[浙贝母化学成分的研究]
[Studies on chemical constituents of Fritillaria thunbergii Miq].
作者信息
Zhang J X, Ma G E, Lao A N, Xu R S
机构信息
Shanghai Institute of Materia Medica, Academia Sinica.
出版信息
Yao Xue Xue Bao. 1991;26(3):231-3.
PMID:1957666
Abstract
A new C-nor-D-homosteroidal alkaloid was isolated from the bulbs of Fritillaria thunbergii Miq. with peimine (I) and peiminine (II), named zhebeinine (III), C27H45O3N, mp. 240-242 degrees C. On the basis of the IR, 1HNMR, 13CNMR and MS of zhebeinine (III), the structure of zhebeinine (III) has been established as 5 alpha, 14 alpha-cevanine-3 beta, 6 alpha, 20 beta-triol.
摘要
从浙贝母鳞茎中与浙贝母碱（I）和去氢浙贝母碱（II）一起分离得到一种新的C-去甲-D-高甾体生物碱，命名为浙贝宁（III），化学式为C27H45O3N，熔点240 - 242℃。根据浙贝宁（III）的红外光谱、核磁共振氢谱、核磁共振碳谱和质谱，已确定浙贝宁（III）的结构为5α，14α-瑟文宁-3β，6α，20β-三醇。
Zotero 插件