Moser Bryan R, Vaughn Steven F
United States Department of Agriculture, Agricultural Research Service, National Center for Agricultural Utilization Research, 1815 N. University St., Peoria, IL 61604, USA.
Bioresour Technol. 2010 Jan;101(2):646-53. doi: 10.1016/j.biortech.2009.08.054. Epub 2009 Sep 8.
Methyl and ethyl esters were prepared from camelina [Camelina sativa (L.) Crantz] oil by homogenous base-catalyzed transesterification for evaluation as biodiesel fuels. Camelina oil contained high percentages of linolenic (32.6 wt.%), linoleic (19.6 wt.%), and oleic (18.6 wt.%) acids. Consequently, camelina oil methyl and ethyl esters (CSME and CSEE) exhibited poor oxidative stabilities and high iodine values versus methyl esters prepared from canola, palm, and soybean oils (CME, PME, and SME). Other fuel properties of CSME and CSEE were similar to CME, PME, and SME, such as low temperature operability, acid value, cetane number, kinematic viscosity, lubricity, sulfur and phosphorous contents, as well as surface tension. As blend components in ultra low-sulfur diesel fuel, CSME and CSEE were essentially indistinguishable from SME and soybean oil ethyl ester blends with regard to low temperature operability, kinematic viscosity, lubricity, and surface tension.
通过均相碱催化酯交换反应,从亚麻荠[Camelina sativa (L.) Crantz]油制备了甲酯和乙酯,以评估其作为生物柴油燃料的性能。亚麻荠油含有高比例的亚麻酸(32.6 wt.%)、亚油酸(19.6 wt.%)和油酸(18.6 wt.%)。因此,与由油菜籽、棕榈和大豆油制备的甲酯(CME、PME和SME)相比,亚麻荠油甲酯和乙酯(CSME和CSEE)的氧化稳定性较差且碘值较高。CSME和CSEE的其他燃料特性与CME、PME和SME相似,如低温操作性、酸值、十六烷值、运动粘度、润滑性、硫和磷含量以及表面张力。作为超低硫柴油燃料的调合组分,CSME和CSEE在低温操作性、运动粘度、润滑性和表面张力方面与SME和大豆油乙酯调合物基本没有区别。