单原子钌催化剂催化水氧化。
Catalytic water oxidation by single-site ruthenium catalysts.
机构信息
Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, USA.
出版信息
Inorg Chem. 2010 Feb 15;49(4):1277-9. doi: 10.1021/ic901437e.
PMID:20058918
Abstract
A series of monomeric ruthenium polypyridyl complexes have been synthesized and characterized, and their performance as water oxidation catalysts has been evaluated. The diversity of ligand environments and how they influence rates and reaction thermodynamics create a platform for catalyst design with controllable reactivity based on ligand variations.
摘要
一系列的单核钌多吡啶配合物已经被合成并进行了表征，并且它们作为水氧化催化剂的性能也得到了评估。配体环境的多样性以及它们如何影响反应速率和反应热力学为基于配体变化的可控反应性催化剂设计提供了一个平台。
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