Department of Chemistry, Ashland University, 401 College Ave, Ashland, OH 44805, USA.
J Hazard Mater. 2010 May 15;177(1-3):1150-2. doi: 10.1016/j.jhazmat.2010.01.016. Epub 2010 Jan 11.
Lead is a potent neurotoxin particularly toxic to young children, and in response to recent poisonings of children and high levels of lead contamination in children's jewelry, US regulatory standards for lead content in these items have become much more stringent. Parents are often advised to throw out suspect items in the trash. While household wastes are generally exempt from consideration as hazardous waste, the potential for leaching of hazardous quantities of lead from such items is unknown. A modified Toxicity Characteristic Leaching Procedure (TCLP), in which intact jewelry components were subjected to leaching, was used to evaluate the potential for leaching of lead from highly leaded jewelry. Of 62 jewelry components tested, 61 exceeded the US regulatory standard for lead of 5mg/L, and leachate lead concentrations averaged 1460 mg/L. Twenty-six of the component items tested yielded TCLP lead concentrations exceeding 1000 mg/L. These results demonstrate that highly leaded jewelry items may leach significant amounts of lead, and provide another reason to remove lead from these products. Furthermore, these results suggest that while the volume of such items in the municipal solid waste (MSW) stream is small, they have the potential to contribute significant quantities of lead to MSW leachates.
铅是一种强效神经毒素,对幼儿尤其有害。鉴于最近发生多起儿童铅中毒事件,以及儿童首饰中含铅量过高的情况,美国对这些产品中铅含量的监管标准已变得严格得多。家长们经常被建议将可疑物品直接扔进垃圾桶。尽管一般家庭废物都不属于危险废物,但这些物品是否存在大量铅浸出的风险尚不清楚。本研究采用改良的毒性特征浸出程序(TCLP),对完整的首饰部件进行浸出实验,评估高铅首饰中铅浸出的可能性。在 62 件首饰部件中,有 61 件超过了美国规定的 5mg/L 的铅含量标准,浸出液中的铅浓度平均为 1460mg/L。有 26 件部件的 TCLP 铅浓度超过 1000mg/L。这些结果表明,高铅含量的首饰可能会浸出大量的铅,这为将这些产品中的铅去除提供了另一个理由。此外,这些结果表明,尽管此类物品在城市固体废物(MSW)中的体积很小,但它们有可能向 MSW 浸出液中贡献大量的铅。