一维金属叠氮配合物由双 EO 桥联三核镍（II）单元构建：合成、结构和磁性。
One-dimensional metal-azido complex constructed by a double EO azido bridged trinuclear nickel(II) unit: synthesis, structure and magnetic properties.
机构信息
Department of Chemistry, Nankai University, Tianjin 300071, China.
出版信息
Dalton Trans. 2010 Feb 7;39(5):1185-7. doi: 10.1039/b915616j. Epub 2009 Nov 5.
The hydrothermal reaction of Ni(NO(3))(2).6H(2)O, NaN(3) phenanthroline and nicotinic acid yielded a one-dimensional (1D) complex, Ni(1.5)(N(3))(2)(phen)(nic) (1) (phen = phenanthroline, nic = nicotinate), which is a new example of the named orbital countercomplementarity-like complex. In 1, the nicotinate shows mu(3)-nic-N,O,O coordination mode, and the azide groups adopt mu(1,1) bridging mode linking Ni(II) ions to form a rare trinuclear Ni(II) unit bridged by a double mu(1,1) azido.
水热反应 Ni(NO(3))(2).6H(2)O、NaN(3) 菲啰啉和烟酸生成了一维（1D）配合物 Ni(1.5)(N(3))(2)(phen)(nic) (1)（phen = 菲啰啉，nic = 烟酸盐），这是命名的轨道互补类似配合物的新实例。在 1 中，烟酸呈现 μ(3)-nic-N,O,O 配位模式，叠氮基团采用 μ(1,1)桥连模式将 Ni(II)离子连接起来，形成罕见的三核 Ni(II)单元，由双 μ(1,1)叠氮桥接。
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