聚二乙酰烯组装体的紫外诱导色性。

UV-induced chromatism of polydiacetylenic assemblies.

机构信息

Key Laboratory of Molecular Engineering of Polymers of Ministry of Education, Department of Macromolecular Science, Fudan University, Shanghai 200438, China.

出版信息

J Phys Chem B. 2010 Feb 25;114(7):2379-82. doi: 10.1021/jp910592y.

DOI:10.1021/jp910592y

PMID:20121117

Abstract

Highly ordered lamellar polydiacetylene nanocomposites are synthesized by assembling polydiacetylene and azobenzene through a ready solution process. The trans-to-cis transition of azobenzene under UV light induces a conformational change of polydiacetylene with a color change from blue to red.

摘要

通过简单的溶液处理方法，将聚二乙炔和偶氮苯组装，合成了具有高度有序层状结构的聚二乙炔纳米复合材料。偶氮苯在紫外光照射下的顺反异构转变诱导了聚二乙炔的构象变化，使其颜色从蓝色变为红色。