硒醚官能化叔膦的通用途径。
Versatile routes to selenoether functionalised tertiary phosphines.
机构信息
Department of Chemistry, Loughborough University, Loughborough, UK LE11 3TU.
出版信息
Dalton Trans. 2010 Jun 14;39(22):5216-8. doi: 10.1039/c0dt00004c. Epub 2010 Apr 19.
PMID:20405074
Abstract
New selenoether functionalised tertiary phosphines, based on aryl (2a, 2b) or alkyl (4) backbones, have been synthesised and characterised. P,Se-chelation has been achieved upon complexation to square-planar Pt(II) (3a) or Pd(II) (3b) metal centres. For 3a and 3b, weak non-covalent M...Se contacts were established using single crystal X-ray crystallography.
摘要
新型硒醚官能化叔膦，基于芳基（2a，2b）或烷基（4）骨架，已被合成和表征。在与平面正方形 Pt(II)（3a）或 Pd(II)（3b）金属中心配位时，实现了 P，Se 螯合。对于 3a 和 3b，使用单晶 X 射线晶体学确定了弱非共价 M...Se 接触。
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