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基于银纳米颗粒聚合物复合材料的湿度传感器。

Silver nanoparticle polymer composite based humidity sensor.

机构信息

School of Chemical and Pharmaceutical Sciences, Dublin Institute of Technology, Kevin St, Dublin, 8, Ireland.

出版信息

Analyst. 2010 Jul;135(7):1645-52. doi: 10.1039/c0an00133c. Epub 2010 Jun 1.

Abstract

Silver nanoparticles were synthesised by a chemical reduction process in order to produce an aqueous colloidal dispersion. The resulting colloids were then characterised by a combination of UV-Vis spectroscopy, dynamic light scattering, X-ray diffraction and transmission electron microscopy and the nanoparticles were found to have an average diameter of 20-22 nm. The Ag/polymer nanocomposites were then applied to platinum interdigital electrodes as sensor coatings and the capability of the resulting sensor as a humidity detector investigated. With the application of 1 V, a current developed which was found to be directly proportional to humidity levels. The sensor gives a reversible, selective and rapid response which is proportional to levels of humidity within the range of 10% RH to 60% RH. An investigation into the mechanism of the sensor's response was conducted and the response was found to correlate well with a second order Langmuir adsorption model.

摘要

采用化学还原法合成了银纳米粒子,以制备水基胶体分散体。所得胶体随后通过紫外-可见光谱、动态光散射、X 射线衍射和透射电子显微镜进行了表征,发现纳米粒子的平均直径为 20-22nm。然后将 Ag/聚合物纳米复合材料应用于铂叉指电极作为传感器涂层,并研究了由此产生的传感器作为湿度探测器的能力。在施加 1V 的情况下,开发出的电流被发现与湿度水平直接成正比。该传感器具有可逆、选择性和快速响应的特点,与 10%RH 至 60%RH 范围内的湿度水平成正比。对传感器响应机制进行了研究,发现响应与二级朗缪尔吸附模型很好地相关。

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