Istanbul Technical University, Chemical Engineering Department, 34469, Maslak, Istanbul, Turkey.
Waste Manag. 2010 Dec;30(12):2631-5. doi: 10.1016/j.wasman.2010.06.005.
The leather industry is an industry which generates a large amount of solid and liquid wastes. Most of the solid wastes originate from the pre-tanning processes while half of it comes from the fleshing step. Raw fleshing wastes which mainly consist of protein and fat have almost no recovery option and the disposal is costly. This study outlines the possibility of using the fleshing waste as an oil source for transesterification reaction. The effect of oil/alcohol molar ratio, the amount of catalyst and temperature on ester production was individually investigated and optimum reaction conditions were determined. The fuel properties of the ester product were also studied according to the EN 14214 standard. Cold filter plugging point and oxidation stability have to be improved in order to use the ester product as an alternative fuel candidate. Besides, this product can be used as a feedstock in lubricant production or cosmetic industry.
制革业是一个产生大量固废和液废的产业。大部分固废源于鞣前准备过程,其中一半来自于浸灰工序。生皮废料主要由蛋白质和脂肪组成,几乎没有回收利用的可能,处理成本高昂。本研究探讨了将生皮废料作为油脂来源进行酯交换反应的可能性。分别考察了油醇摩尔比、催化剂用量和温度对酯产量的影响,确定了最佳反应条件。还根据 EN 14214 标准研究了酯产物的燃料性能。为了将酯产物用作替代燃料候选物,还需要改进冷滤堵塞点和氧化稳定性。此外,该产品可用作润滑油或化妆品生产的原料。