中规中矩的士兵效应：萘二酰亚胺纳米管中的手性放大。
The sergeants-and-soldiers effect: chiral amplification in naphthalenediimide nanotubes.
机构信息
University Chemical Laboratory, University of Cambridge, Lensfield Road, Cambridge, UKCB2 1EW.
出版信息
Org Biomol Chem. 2010 Oct 7;8(19):4274-80. doi: 10.1039/c0ob00027b. Epub 2010 Jul 9.
Self-assembling naphthalenediimide (NDI)-based helical organic nanotubes display sergeants-and-soldiers behaviour, chiral monomers imposing a supramolecular structure upon achiral monomers. Several achiral NDI monomers were synthesised and their ability to incorporate into supramolecular nanotubes was studied. Nanotubes containing predominantly the most effective soldier, derived from 1-aminocyclopropane-carboxylic acid, are effective hosts for C(60).
自组装萘二酰亚胺（NDI）基螺旋有机纳米管表现出“兵和将”行为，手性单体对手性单体施加超分子结构。合成了几种非手性 NDI 单体，并研究了它们掺入超分子纳米管的能力。主要含有最有效“士兵”的纳米管，来源于 1-氨基环丙烷羧酸，是 C（60）的有效主体。
Zotero 插件