树枝状化和金属化反式-2 C60 四芳基卟啉——一种制备水溶性给体-受体化合物的通用方法。
Dendronizing and metalating trans-2 C60 tetraaryl porphyrins--a versatile approach toward water-soluble donor-acceptor conjugates.
机构信息
Department of Chemistry and Pharmacy and Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestrasse 42, 91054 Erlangen, Germany.
出版信息
Chemistry. 2010 Sep 17;16(35):10797-807. doi: 10.1002/chem.201000760.
PMID:20669192
Abstract
We have realized for the first time a series of truly water-soluble and tightly coupled porphyrin/C(60) electron-donor-acceptor conjugates in which the charge separation and charge recombination dynamics are controlled by modifying the nature of the dendrimer and/or the choice of the central metal atom.
摘要
我们首次实现了一系列真正水溶性且紧密偶联的卟啉/C(60) 电子给体-受体化合物，其中通过修饰树枝状大分子的性质和/或选择中心金属原子来控制电荷分离和电荷复合动力学。
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