Department of Nanoengineering, University of California San Diego, La Jolla, California 92093, USA.
J Am Chem Soc. 2010 Oct 20;132(41):14403-5. doi: 10.1021/ja1072349.
Fuel-free magnetically driven propulsion of flexible Au/Ag/Ni nanowires, with a gold 'head' and nickel 'tail', linked by a partially dissolved and weakened silver bridge, is described. The flexible bridge facilitates the cyclic mechanical deformations under an external rotating magnetic field. Under such a field the nickel segment starts to rotate, facilitating the rotation of the gold segment at a different amplitude, hence breaking the system symmetry and inducing the movement. Forward ('pushing') and backward ('pulling') magnetically powered locomotion and a precise On/Off motion control are achieved by tailoring the length of the nickel and gold segments and modulating the magnetic field, respectively. Efficient locomotion in urine samples and in high-salt media is illustrated. The new magnetic nanowire swimmers can be prepared in large scale using a simple template electrodeposition protocol and offer considerable promise for diverse practical applications.
无燃料的磁驱动柔性金/银/镍纳米线推进,其具有金“头部”和镍“尾部”,由部分溶解和弱化的银桥连接。柔性桥便于在外加旋转磁场下进行循环机械变形。在外磁场作用下,镍段开始旋转,从而促进金段以不同的幅度旋转,从而打破系统对称性并引起运动。通过调整镍段和金段的长度和调节磁场,分别实现了向前(“推动”)和向后(“拉动”)的磁动力运动以及精确的开/关运动控制。在尿液样本和高盐介质中的高效运动得到了说明。新的磁性纳米线游泳者可以使用简单的模板电沉积协议大规模制备,并为各种实际应用提供了很大的前景。