室温条件下，水相中烯基和烷基卤化物的 Negishi 型立体选择性偶联反应。
Stereoselective Negishi-like couplings between alkenyl and alkyl halides in water at room temperature.
机构信息
Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106, United States.
出版信息
Org Lett. 2010 Nov 5;12(21):4742-4. doi: 10.1021/ol101885t.
Abstract
Mix in water and then stir. That is all that is required in this new approach to stereoselective sp(3)-sp(2) cross-couplings between an alkyl and alkenyl halide. Prior formation of organozinc reagents is not required.
摘要
在水中混合，然后搅拌。这就是这种新方法在烷基和烯基卤化物之间进行立体选择性 sp(3)-sp(2)交叉偶联时所需的全部操作。不需要预先形成有机锌试剂。
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