顺-顺-反-双（乙腈-κN）二氯双（三苯基膦-κP）钌（II）乙腈溶剂合物
cis-cis-trans-Bis(acetonitrile-κN)dichloridobis(triphenyl-phosphine-κP)ruthenium(II) acetonitrile disolvate.
作者信息
Al-Far Ahmad M, Slaughter Legrande M
机构信息
Department of Chemistry, Oklahoma State University, Stillwater, OK 74078, USA.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 12;64(Pt 1):m184. doi: 10.1107/S1600536807065968.
The title compound, [RuCl(2)(C(2)H(3)N)(2)(C(18)H(15)P)(2)]·2C(2)H(3)N, was obtained upon stirring an acetonitrile/ethanol solution of [RuCl(2)(PPh(3))(3)]. In the crystal structure, each Ru(II) ion is coordinated by two Cl [Ru-Cl = 2.4308 (7) and 2.4139 (7) Å], two N [Ru-N = 2.016 (2) and 2.003 (2) Å], and two P [Ru-P = 2.3688 (7) and 2.3887 (7) Å] atoms in a distorted octa-hedral geometry. Packing inter-actions include typical C-H⋯π contacts involving phenyl groups as well as weak hydrogen bonds between CH(3)CN methyl H atoms and Cl or solvent CH(3)CN N atoms.
标题化合物[RuCl₂(C₂H₃N)₂(C₁₈H₁₅P)₂]·2C₂H₃N是在搅拌[RuCl₂(PPh₃)₃]的乙腈/乙醇溶液时得到的。在晶体结构中，每个Ru(II)离子由两个Cl原子[Ru-Cl = 2.4308 (7) 和2.4139 (7) Å]、两个N原子[Ru-N = 2.016 (2) 和2.003 (2) Å]以及两个P原子[Ru-P = 2.3688 (7) 和2.3887 (7) Å]配位，呈扭曲的八面体几何构型。堆积相互作用包括涉及苯基的典型C-H⋯π接触以及CH₃CN甲基H原子与Cl或溶剂CH₃CN N原子之间的弱氢键。
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