Fun Hoong-Kun, John Jain, Jebas Samuel Robinson, Balasubramanian T
Acta Crystallogr Sect E Struct Rep Online. 2008 May 3;64(Pt 6):m753. doi: 10.1107/S1600536808012166.
In the crystal structure of the title compound, Cu(C(2)H(3)O(3))Cl(H(2)O), the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. Two O atoms from a chelating glycolate anion, an O atom from a coordinated water mol-ecule and a chloride anion comprise the basal plane. A chloride ion from a neighbouring unit occupies the apical position and these Cu-Cl-Cu bridges link the aqua-glycolatocopper(II) units into one-dimensional chains along the [001] direction. These chains are connected by O-H⋯O and O-H⋯Cl hydrogen bonds, forming an infinite three-dimensional polymeric network.
在标题化合物[Cu(C₂H₃O₃)Cl(H₂O)]ₙ的晶体结构中,Cu(II)离子呈五配位,具有扭曲的四方锥几何构型。来自螯合乙醇酸根阴离子的两个O原子、来自配位水分子的一个O原子和一个氯离子构成了基面。来自相邻单元的一个氯离子占据顶端位置,这些Cu-Cl-Cu桥将水合乙醇酸铜(II)单元沿[001]方向连接成一维链。这些链通过O-H⋯O和O-H⋯Cl氢键相连,形成一个无限的三维聚合物网络。