三笼基沸石型金属有机骨架与 Johnson 型十二面体的协同组装。
Cooperative assembly of three-ring-based zeolite-type metal-organic frameworks and Johnson-type dodecahedra.
机构信息
Department of Chemistry and Biochemistry, California State University, Long Beach, 1250 Bellflower Boulevard, Long Beach, CA 90840, USA.
出版信息
Angew Chem Int Ed Engl. 2011 Feb 18;50(8):1849-52. doi: 10.1002/anie.201006882. Epub 2011 Jan 21.
Abstract
One synthetic strategy led to the preparation of both 3-ring-based zeolite-type metal-organic frameworks (NPO-type) and Johnson-type metal-organic polyhedra. The strategy is based on the cooperative assembly of 4-connected indium nodes with two symmetry-complementary ligands (one serves to generate 3-rings and the other crosslinks 3-rings). Photocatalytic H production experiments demonstrated these NPO-zeolite compounds behave as semiconductors and exhibit photocatalytic activity for the generation of dihydrogen from water under ultraviolet irradiation.
摘要
一种合成策略导致了基于 3 元环的沸石型金属有机骨架（NPO 型）和 Johnson 型金属有机多面体的制备。该策略基于 4 连接的铟节点与两个对称互补配体的协同组装（一个用于生成 3 元环，另一个交联 3 元环）。光催化产氢实验表明，这些 NPO 沸石化合物表现为半导体，并在紫外光照射下从水中产生氢气具有光催化活性。
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本文引用的文献
1
Bridging-ligand-substitution strategy for the preparation of metal-organic polyhedra.
Nat Chem. 2010 Oct;2(10):893-8. doi: 10.1038/nchem.803. Epub 2010 Aug 22.
2
Extra-large pore zeolite (ITQ-40) with the lowest framework density containing double four- and double three-rings.
Proc Natl Acad Sci U S A. 2010 Aug 10;107(32):13997-4002. doi: 10.1073/pnas.1003009107. Epub 2010 Jul 26.
3
The synthesis of an extra-large-pore zeolite with double three-ring building units and a low framework density.
Angew Chem Int Ed Engl. 2010 Jul 5;49(29):4986-8. doi: 10.1002/anie.201001506.
4
Self-assembled M24L48 polyhedra and their sharp structural switch upon subtle ligand variation.
Science. 2010 May 28;328(5982):1144-7. doi: 10.1126/science.1188605. Epub 2010 Apr 29.
5
Edge-directed [(M2)2L4] tetragonal metal-organic polyhedra decorated using a square paddle-wheel secondary building unit.
Chem Commun (Camb). 2010 Mar 28;46(12):2049-51. doi: 10.1039/b925335a. Epub 2010 Feb 15.
6
Coronene nanophase within coordination spheres: increased solubility of C60.
J Am Chem Soc. 2010 Mar 3;132(8):2544-5. doi: 10.1021/ja910836h.
7
In Situ Synthesis of Tetradentate Dye for Construction of Three-Dimensional Homochiral Phosphor.
Chem Mater. 2008;20(17):5457-5459. doi: 10.1021/cm801385m.
8
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J Am Chem Soc. 2009 Dec 16;131(49):17753-5. doi: 10.1021/ja905557z.
9
Systematic metal variation and solvent and hydrogen-gas storage in supramolecular nanoballs.
Angew Chem Int Ed Engl. 2009;48(47):8919-22. doi: 10.1002/anie.200903863.
10
Synthesis and structure of chemically stable metal-organic polyhedra.
J Am Chem Soc. 2009 Sep 9;131(35):12532-3. doi: 10.1021/ja905101s.
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