Faculty of Sciences, Laboratory of Environmental Analytical Chemistry (05/UR/12-03), 7021, Bizerte, Zarzouna, Tunisia.
Bull Environ Contam Toxicol. 2011 May;86(5):539-44. doi: 10.1007/s00128-011-0258-3. Epub 2011 Apr 5.
The concentrations of 20 Polychlorinated biphenyls (PCBs) were determined in 12 superficial sediments collected from The Ghar El Melh lagoon. Sediment samples were extracted by Soxhlet and analyzed by Gas chromatography with electron capture detector. The concentrations of PCBs, as sum of the 20 congeners, ranged from not detected to 3.987 ng/g on a dry weight basis, with a predominance of highly chlorinated (penta- and hepta-chlorobiphenyls) congeners. No significant correlation was found between the total PCB concentrations and organic carbon content suggesting that sediment organic carbon content did not play an important role in controlling the PCBs levels in the sediments. PCB levels in sediments were compared with Sediments Quality Guidelines (ERM-ERL indexes) for evaluation probable toxic effects on marine organism. The PCBs concentrations were lower than ERM and ERL values for all the collected samples.
从加尔梅尔勒泻湖采集了 12 份表层沉积物,测定了其中 20 种多氯联苯(PCBs)的浓度。通过索氏提取法对沉积物样品进行提取,并用带电子俘获检测器的气相色谱法进行分析。PCBs 的浓度(20 种同系物的总和)以干重为基础,范围从未检出到 3.987ng/g,以高氯化(五氯和七氯联苯)同系物为主。总 PCB 浓度与有机碳含量之间没有发现显著相关性,这表明沉积物有机碳含量对控制沉积物中 PCBs 水平没有重要作用。将沉积物中的 PCBs 水平与沉积物质量指南(ERM-ERL 指数)进行了比较,以评估其对海洋生物可能产生的毒性影响。所有采集的样本中,PCBs 浓度均低于 ERM 和 ERL 值。