Ming-Hsieh Department of Electrical Engineering, University of Southern California, Los Angeles, CA 90089, USA.
Nanotechnology. 2011 Jun 17;22(24):245201. doi: 10.1088/0957-4484/22/24/245201. Epub 2011 Apr 20.
The application of silver nanowire films as transparent conductive electrodes has shown promising results recently. In this paper, we demonstrate the application of a simple spray coating technique to obtain large scale, highly uniform and conductive silver nanowire films on arbitrary substrates. We also integrated a polydimethylsiloxane (PDMS)-assisted contact transfer technique with spray coating, which allowed us to obtain large scale high quality patterned films of silver nanowires. The transparency and conductivity of the films was controlled by the volume of the dispersion used in spraying and the substrate area. We note that the optoelectrical property, σ(DC)/σ(Op), for various films fabricated was in the range 75-350, which is extremely high for transparent thin film compared to other candidate alternatives to doped metal oxide film. Using this method, we obtain silver nanowire films on a flexible polyethylene terephthalate (PET) substrate with a transparency of 85% and sheet resistance of 33 Ω/sq, which is comparable to that of tin-doped indium oxide (ITO) on flexible substrates. In-depth analysis of the film shows a high performance using another commonly used figure-of-merit, Φ(TE). Also, Ag nanowire film/PET shows good mechanical flexibility and the application of such a conductive silver nanowire film as an electrode in a touch panel has been demonstrated.
最近,将银纳米线薄膜应用于透明导电电极已显示出很有前景的结果。在本文中,我们展示了一种简单的喷涂技术,可在任意基底上获得大规模、高度均匀且导电的银纳米线薄膜。我们还将聚二甲基硅氧烷(PDMS)辅助的接触转移技术与喷涂技术相结合,从而获得了大规模高质量的银纳米线图案化薄膜。通过喷涂中使用的分散体的体积和基底面积来控制薄膜的透光率和导电性。我们注意到,各种所制备的薄膜的光电性能,σ(DC)/σ(Op),在 75-350 的范围内,与掺杂金属氧化物薄膜等其他候选替代物相比,对于透明薄膜而言非常高。使用这种方法,我们在柔性聚对苯二甲酸乙二醇酯(PET)基底上获得了银纳米线薄膜,其透光率为 85%,方阻为 33 Ω/sq,与柔性基底上的掺锡氧化铟(ITO)相当。对薄膜的深入分析表明,使用另一个常用的性能指标 Φ(TE),其性能也很高。此外,Ag 纳米线薄膜/PET 还表现出良好的机械柔韧性,并且已经展示了将这种导电银纳米线薄膜用作触摸面板中的电极的应用。