高氯酸4-碘代苯胺-18-冠-6包合物
4-Iodo-anilinium perchlorate 18-crown-6 clathrate.
作者信息
Zhang Yi, Zhao Min-Min
机构信息
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 12;67(Pt 3):o596. doi: 10.1107/S1600536811004260.
Abstract
In the title compound, C(6)H(7)IN(+)·ClO(4) (-)·C(12)H(24)O(6), the proton-ated 4-iodo-anilinium cation inter-acts with the 18-crown-6 through three N-H⋯O hydrogen bonds, forming a rotator-stator-like structure. The cation, anion and 18-crown-6 mol-ecule all have crystallographically imposed mirror symmetry.
摘要
在标题化合物C(6)H(7)IN(+)·ClO(4) (-)·C(12)H(24)O(6)中，质子化的4-碘代苯胺阳离子通过三个N-H⋯O氢键与18-冠-6相互作用，形成类似转子-定子的结构。阳离子、阴离子和18-冠-6分子均具有晶体学上的镜像对称性。
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