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(1RS,6SR)-Ethyl 4,6-bis-(4-fluoro-phen-yl)-2-oxocyclo-hex-3-ene-1-carboxyl-ate.

作者信息

Dutkiewicz Grzegorz, Narayana B, Veena K, Yathirajan H S, Kubicki Maciej

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 12;67(Pt 2):o336. doi: 10.1107/S1600536811000171.

Abstract

In the crystal structure of the title compound, C(21)H(18)F(2)O(3), the cyclo-hexene ring has a slightly distorted sofa conformation; the two benzene rings are inclined by 76.27 (8)° and their planes make dihedral angles of 16.65 (10) and 67.53 (7)° with the approximately planar part of the cyclo-hexenone ring [maximum deviation 0.044 (2) Å, while the sixth atom is displaced by 0.648 (3) Å from this plane]. In the crystal, weak inter-molecular C-H⋯O, C-H⋯F and C-H⋯π inter-actions join mol-ecules into a three-dimensional structure.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a55/3051537/bdd3ff7536a1/e-67-0o336-fig1.jpg

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