通过有氧光氧化和碘化碘脱除，从苯乙烯一锅法无金属合成苯乙酮。
One-pot metal-free syntheses of acetophenones from styrenes through aerobic photo-oxidation and deiodination with iodine.
机构信息
Gifu Pharmaceutical University, Gifu, Japan.
出版信息
Org Lett. 2011 May 20;13(10):2576-9. doi: 10.1021/ol200681k. Epub 2011 Apr 27.
PMID:21524090
Abstract
A one-pot synthetic protocol of acetophenones from styrenes with molecular oxygen, visible light, and molecular iodine is reported. This procedure involves aerobic photo-oxidation and deiodination in one pot and provides the first report of metal-free direct syntheses of acetophenones from styrenes.
摘要
本文报道了一种由苯乙烯、分子氧、可见光和分子碘一锅合成苯乙酮的方法。该方法涉及一锅有氧光氧化和脱碘反应，为无金属直接合成苯乙酮提供了首例报道。
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