Suh Seung Wook, Kim Chong-Hyeak, Kim Inn Hoe
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 8;65(Pt 9):m1054. doi: 10.1107/S1600536809030931.
The Zn(II) ion in the title complex, [Zn(NCS)(2)(C(7)H(6)N(2)S)(2)], is tetra-hedrally coordinated within an N(4) donor set defined by two N atoms of two terminal isothio-cyanate ligands and by two heterocyclic N atoms of two different 2-amino-benzothia-zole ligands. This arrangement is stabilized by intra-molecular N-H⋯N hydrogen bonds. In the crystal structure, mol-ecules are linked through N-H⋯S hydrogen bonds to form a two-dimensional array.
标题配合物[Zn(NCS)₂(C₇H₆N₂S)₂]中的Zn(II)离子在由两个末端异硫氰酸酯配体的两个N原子以及两个不同的2-氨基苯并噻唑配体的两个杂环N原子所定义的N₄供体集合内呈四面体配位。这种排列通过分子内N-H⋯N氢键得以稳定。在晶体结构中,分子通过N-H⋯S氢键相连形成二维阵列。