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μ-4-Benzoyl-1-(1-oxido-2-naphthyl-carbon-yl)thio-semicarbazidato(4-)]bis-[pyridine-copper(II).

作者信息

Zhang Wen, Gao Jin-Ping, Shi Xue-Feng, Li Da-Cheng

机构信息

College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 17;65(Pt 11):m1363. doi: 10.1107/S1600536809040951.

Abstract

In the title dinuclear complex, [Cu(2)(C(19)H(11)N(3)O(3)S)(C(5)H(5)N)(2)], the two Cu(II) centers have different coordination environments, viz. N(2)OS and N(2)O(2), each exhibiting a distorted square-planar geometry. π-π inter-actions between the aromatic rings of neighbouring complexes [centroid-centroid distance = 3.856 (5) Å] link pairs of mol-ecules into centrosymmetric dimers, which are further packed into stacks along the b axis with relatively short Cu⋯Cu separations of 3.482 (1) Å. Weak inter-molecular C-H⋯N hydrogen bonds help to consolidate the crystal packing.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f17/2971176/721d3f80f735/e-65-m1363-fig1.jpg

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