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2-乙基-6,6-亚乙基二硫基-7-甲氧基甲基-1,2,3,4,5,6-六氢-1,5-亚甲基氮杂环辛并[4,3-b]吲哚-3-酮

2-Ethyl-6,6-ethyl-enedisulfanediyl-7-methoxy-methyl-1,2,3,4,5,6-hexa-hydro-1,5-methano-azocino[4,3-b]indol-3-one.

作者信息

Tercan Barış, Sahin Ertan, Patır Süleyman, Hökelek Tuncer

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 9;66(Pt 2):o328. doi: 10.1107/S160053681000067X.

Abstract

The title compound, C(20)H(24)N(2)O(2)S(2), consists of a tetra-cyclic ring system containing an azocino skeleton with ethyl, dithiol-ane and methoxy-methyl groups as substituents. The benzene and five-membered rings are nearly coplanar, with a dihedral angle of 2.78 (11)°. The dithiol-ane ring adopts an envelope conformation. In the crystal structure, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into chains nearly parallel to the c axis. Two C-H⋯π inter-actions are also present.

摘要

标题化合物C(20)H(24)N(2)O(2)S(2)由一个四环体系组成,该体系包含一个偶氮辛环骨架,带有乙基、二硫戊环和甲氧基甲基作为取代基。苯环和五元环几乎共面,二面角为2.78 (11)°。二硫戊环环采取信封构象。在晶体结构中,分子间的C-H⋯O氢键将分子连接成几乎平行于c轴的链。还存在两种C-H⋯π相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0192/2979738/ab55bdec2102/e-66-0o328-fig1.jpg

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