水合-[N-苯基-2-(喹啉-8-基氧基)乙酰胺]二硝酸锌(II)
Aqua-[N-phenyl-2-(quinolin-8-yl-oxy)acetamide]dinitratozinc(II).
作者信息
Wu Wei-Na, Wang Yuan, Zhang Ai-Yun, Zhao Rui-Qi, Wang Qiu-Fen
机构信息
Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo 454000, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 13;66(Pt 3):m288. doi: 10.1107/S160053681000471X.
In the title complex, [Zn(NO(3))(2)(C(17)H(14)N(2)O(2))(H(2)O)], the six-coordinated Zn atom is in a distorted octa-hedral geometry, the donor centers being two O atoms and one N atom from the tridentate organic ligand, a water O atom and two O atoms from two monodentate nitrate ions. In the crystal, O-H⋯O hydrogen bonds between the coordinated water mol-ecules and nitrate O atoms and N-H⋯O hydrogen bonds between the main ligand and nitrate O atoms consolidate the three-dimensional network.
在标题配合物[Zn(NO₃)₂(C₁₇H₁₄N₂O₂)(H₂O)]中，六配位的Zn原子处于扭曲的八面体几何构型，供体中心为来自三齿有机配体的两个O原子和一个N原子、一个配位水分子的O原子以及来自两个单齿硝酸根离子的两个O原子。在晶体中，配位水分子与硝酸根O原子之间的O—H⋯O氢键以及主配体与硝酸根O原子之间的N—H⋯O氢键巩固了三维网络结构。
Zotero 插件