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链状聚[[[双-(μ-4-羟基苯甲酸根)双-[(4-羟基苯甲酸根)锰(II)]]-二-μ-4,4'-联吡啶] 4,4'-联吡啶溶剂合物四水合物]

catena-Poly[[[bis-(μ-4-hydroxy-benzoato)bis-[(4-hydroxy-benzoato)manganese(II)]]-di-μ-4,4'-bipyridine] 4,4'-bipyridine disolvate tetra-hydrate].

作者信息

Zhao Qi-Hua, Zhao Lei, Wang Kun-Miao, Zhou Hong

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 3;66(Pt 4):m358. doi: 10.1107/S1600536810007245.

Abstract

In the polymeric title complex, {[Mn(O(2)CC(6)H(4)-p-OH)(2)(C(10)H(8)N(2))]·C(10)H(8)N(2)·2H(2)O}(n), the Mn(II) atom is coordinated in a distorted octa-hedral geometry defined by four O atoms from three different carboxyl-ate ligands and two trans-N atoms from two 4,4'-bipyridine ligands. In the crystal structure, an extensive range of O-H⋯O and O-H⋯N hydrogen bonds link the complex and all non-coordinated mol-ecules into a three-dimensional network.

摘要

在聚合标题配合物{[Mn(O₂CC₆H₄-p-OH)₂(C₁₀H₈N₂)]·C₁₀H₈N₂·2H₂O}ₙ中,Mn(II)原子以扭曲的八面体几何构型配位,该构型由来自三个不同羧酸根配体的四个O原子和来自两个4,4'-联吡啶配体的两个反式N原子确定。在晶体结构中,广泛的O—H⋯O和O—H⋯N氢键将配合物和所有未配位分子连接成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d7a/2983832/93694139e432/e-66-0m358-fig1.jpg

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