Zhao Qi-Hua, Zhao Lei, Wang Kun-Miao, Zhou Hong
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 3;66(Pt 4):m358. doi: 10.1107/S1600536810007245.
In the polymeric title complex, {[Mn(O(2)CC(6)H(4)-p-OH)(2)(C(10)H(8)N(2))]·C(10)H(8)N(2)·2H(2)O}(n), the Mn(II) atom is coordinated in a distorted octa-hedral geometry defined by four O atoms from three different carboxyl-ate ligands and two trans-N atoms from two 4,4'-bipyridine ligands. In the crystal structure, an extensive range of O-H⋯O and O-H⋯N hydrogen bonds link the complex and all non-coordinated mol-ecules into a three-dimensional network.
在聚合标题配合物{[Mn(O₂CC₆H₄-p-OH)₂(C₁₀H₈N₂)]·C₁₀H₈N₂·2H₂O}ₙ中,Mn(II)原子以扭曲的八面体几何构型配位,该构型由来自三个不同羧酸根配体的四个O原子和来自两个4,4'-联吡啶配体的两个反式N原子确定。在晶体结构中,广泛的O—H⋯O和O—H⋯N氢键将配合物和所有未配位分子连接成三维网络。