(E)-1,1'-双[(E)-丁-2-烯基]-3,3'-(丙烷-1,3-二亚基)双-(1H-苯并咪唑-3-鎓)二溴化物一水合物
(E)-1,1'-Bis[(E)-but-2-en-yl]-3,3'-(propane-1,3-di-yl)bis-(1H-benzimidazol-3-ium) dibromide monohydrate.
作者信息
Akkurt Mehmet, Yıldırım Sema Öztürk, Sireci Nihat, Küçükbay Hasan, Büyükgüngör Orhan
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 18;64(Pt 11):o2136-7. doi: 10.1107/S160053680803095X.
The title compound, C(25)H(30)N(4) (2+)·2Br(-)·H(2)O, was synthesized from 1,1'-propyl-enedibenzimidazole and (E)-1-bromo-but-2-ene in dimethyl-formamide solution. The two benzimidazole ring systems are essentially planar, with maximum deviations of 0.011 (4) and 0.023 (3) Å. The dihedral angle between these two ring systems is 25.87 (15)°. The crystal structure is stabilized by inter-molecular O-H⋯Br and C-H⋯Br hydrogen-bonding inter-actions. Atmospheric water was incorporated into the crystal structure.
标题化合物C(25)H(30)N(4)(2+)·2Br(-)·H(2)O是由1,1'-亚丙基二苯并咪唑和(E)-1-溴-2-丁烯在二甲基甲酰胺溶液中合成的。两个苯并咪唑环系基本呈平面状，最大偏差分别为0.011 (4) Å和0.023 (3) Å。这两个环系之间的二面角为25.87 (15)°。晶体结构通过分子间的O-H⋯Br和C-H⋯Br氢键相互作用得以稳定。大气中的水被纳入晶体结构中。
Zotero 插件