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Di-μ-chlorido-bis-{bis-[3,5-dimethyl-pyrazol-1-yl-κN)methane]iron(II)} bis-[tetra-chloridoferrate(III)].

作者信息

Xia Hongying, Liu Yuelong

机构信息

College of Chemistry and Chemical Engineering, Jiangxi Science and Technology Normal University, Nanchang 330013, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):m1504. doi: 10.1107/S1600536808035253.

Abstract

In the title complex, [Fe(2)Cl(2)(C(11)H(16)N(4))(4)]FeCl(4), the asymmetric unit is composed of one and a half units of Fe(bdmpm)(2)Cl(FeCl(4))(2)(bdmpm = bis(bis(3,5-dimethyl-pyrazol-1-yl)methane). The three independent Fe(II) atom have a distorted octa-hedral coordination geometry comprising two bridging chloride anions and four N atoms from two bis-(3,5-dimethyl-pyrazol-1-yl)methane ligands. The Fe(III) atom has a tetra-hedral coordination geometry comprising four chloride anions.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d3d/2959963/dcf076c20bf6/e-64-m1504-fig1.jpg

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