Lush Shie Fu, Shen Fwu Ming
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 2;66(Pt 11):o2701. doi: 10.1107/S160053681003816X.
In the crystal structure of the title compound, C(12)H(14)N(2) (2+)·2C(7)H(5)O(3) (-), the cations and anions are linked via N-H⋯O hydrogen bonds and weak inter-molecular C-H⋯O inter-actions also occur. π-π stacking is observed between the nearly parallel benzene and pyridine rings [dihedral angle = 6.03 (8)°], the centroid-centroid separation being 3.7546 (16) Å. The 4,4'-(ethane-1,2-diyl)dipyridinium cation is centrosymmetric and the mid-point of the ethyl-ene C-C bond is located on an inversion center. An intra-molecular O-H⋯O hydrogen bond occurs in the anion.
在标题化合物C(12)H(14)N(2)(2+)·2C(7)H(5)O(3)(-)的晶体结构中,阳离子和阴离子通过N-H⋯O氢键相连,同时也存在弱的分子间C-H⋯O相互作用。在近乎平行的苯环和吡啶环之间观察到π-π堆积[二面角 = 6.03 (8)°],质心间距为3.7546 (16) Å。4,4'-(乙烷-1,2-二基)二吡啶鎓阳离子是中心对称的,乙烯C-C键的中点位于一个反演中心上。阴离子中存在分子内O-H⋯O氢键。