8β-乙酰氧基-14α-苯甲酰氧基-N-甲基-13β,15α-二羟基-1α,6α,16β-三甲氧基-4β-(甲氧基甲基)乌头烷：从“附子”中分离得到的次乌头碱。
8β-Acet-oxy-14α-benzo-yloxy-N-methyl-13β,15α-dihy-droxy-1α,6α,16β-trimeth-oxy-4β-(meth-oxy-meth-yl)aconitane: hypaconitine isolated from 'fuzi'.
作者信息
Zheng Ling-Li, Li Yan, Zi Tie-Ying, Yuan Ming-Yong
机构信息
The First Affiliated Hospital, Chengdu Medical College, Xindu 610500, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 9;66(Pt 11):o2787-8. doi: 10.1107/S1600536810039887.
Abstract
The title compound, C(33)H(45)NO(10), has an aconitine carbon skeleton with four six-membered rings and two five-membered rings. The five-membered rings adopt envelope configurations and the six-membered N-containing heterocyclic ring displays a chair conformation. Two intra-molecular O-H⋯O hydrogen bonds occur.
摘要
标题化合物C(33)H(45)NO(10)具有乌头碱碳骨架，包含四个六元环和两个五元环。五元环呈信封式构象，含氮六元杂环呈椅式构象。存在两个分子内O-H⋯O氢键。
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