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8β-乙酰氧基-14α-苯甲酰氧基-N-甲基-13β,15α-二羟基-1α,6α,16β-三甲氧基-4β-(甲氧基甲基)乌头烷：从“附子”中分离得到的次乌头碱。

8β-Acet-oxy-14α-benzo-yloxy-N-methyl-13β,15α-dihy-droxy-1α,6α,16β-trimeth-oxy-4β-(meth-oxy-meth-yl)aconitane: hypaconitine isolated from 'fuzi'.

作者信息

Zheng Ling-Li, Li Yan, Zi Tie-Ying, Yuan Ming-Yong

机构信息

The First Affiliated Hospital, Chengdu Medical College, Xindu 610500, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 9;66(Pt 11):o2787-8. doi: 10.1107/S1600536810039887.

DOI:10.1107/S1600536810039887
PMID:21588985
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3009068/
Abstract

The title compound, C(33)H(45)NO(10), has an aconitine carbon skeleton with four six-membered rings and two five-membered rings. The five-membered rings adopt envelope configurations and the six-membered N-containing heterocyclic ring displays a chair conformation. Two intra-molecular O-H⋯O hydrogen bonds occur.

摘要

标题化合物C(33)H(45)NO(10)具有乌头碱碳骨架，包含四个六元环和两个五元环。五元环呈信封式构象，含氮六元杂环呈椅式构象。存在两个分子内O-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/275e/3009068/347d4b3b6bc4/e-66-o2787-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/275e/3009068/d8d46f6c2d00/e-66-o2787-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/275e/3009068/347d4b3b6bc4/e-66-o2787-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/275e/3009068/d8d46f6c2d00/e-66-o2787-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/275e/3009068/347d4b3b6bc4/e-66-o2787-fig2.jpg

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本文引用的文献

1
8β-Acet-oxy-14α-benzo-yloxy-N-ethyl-3α,10β,13β,15α-tetra-hydr-oxy-1α,6α,16β-trimeth-oxy-4β-(methoxy-methyl-ene)aconitane: aconifine from Aconitum karakolicum Rapaics.
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 10;65(Pt 7):o1543-4. doi: 10.1107/S1600536809021436.
2
3-Deoxy-aconitine from the root of Aconitum Carmichaeli Debx.来源于乌头（Aconitum Carmichaeli Debx.）根的3-去氧乌头碱
Acta Crystallogr Sect E Struct Rep Online. 2010 May 15;66(Pt 6):o1342. doi: 10.1107/S1600536810016922.
3
Mesaconitine.新乌头碱
Acta Crystallogr Sect E Struct Rep Online. 2008 May 10;64(Pt 6):o1033-4. doi: 10.1107/S1600536808013147.
4
Diterpenoid alkaloids.二萜生物碱。
Nat Prod Rep. 2010 Apr;27(4):529-70. doi: 10.1039/b916679c. Epub 2010 Feb 15.
5
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.