双[μ-3-(2-羟基苯基)丙烯酸根合]双-{水合-(4,4'-联吡啶)-双-[3-(2-羟基苯基)丙烯酸根合]钇(III)} 4,4'-联吡啶二溶剂化物
Bis[μ-3-(2-hy-droxy-phen-yl)propenoato]bis-{aqua-(4,4'-bipyridine)-bis-[3-(2-hydroxy-phen-yl)propenoato]yttrium(III)} 4,4'-bipyridine disolvate.
作者信息
Zhang Chun-Yan, Fu Jun-Dan, Wen Yi-Hang
机构信息
Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 6;66(Pt 12):m1519. doi: 10.1107/S1600536810044831.
The title compound, [Y(2)(C(9)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2C(10)H(8)N(2), contains two eight-coordinated Y(III) ions, which are linked by two carboxyl-ate groups from two 2-hy-droxy-cinnamate anions, leading to a centrosymmetric dinuclear structure surrounded by solvent 4,4'-bipyridine mol-ecules. It forms a three-dimensional framework connected by extensive O-H⋯O and O-H⋯N hydrogen-bonding inter-actions.
标题化合物[Y₂(C₉H₇O₃)₆(C₁₀H₈N₂)₂(H₂O)₂]·2C₁₀H₈N₂包含两个八配位的Y(III)离子，它们通过来自两个2-羟基肉桂酸根阴离子的两个羧酸根基团相连，形成一个中心对称的双核结构，周围环绕着溶剂4,4'-联吡啶分子。它通过广泛的O-H⋯O和O-H⋯N氢键相互作用形成三维框架。
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