四[1-苯基-3-(1H-1,2,4-三唑-1-基-κN)丙-1-酮]双(硫氰酸根-κN)锰(II)
Tetra-kis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN)propan-1-one]bis-(thio-cyanato-κN)manganese(II).
作者信息
Cai Hua, Guo Ying, Li Jian-Gang
机构信息
College of Science, Civil Aviation University of China, Tianjin 300300, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 20;66(Pt 12):m1605. doi: 10.1107/S1600536810047112.
In the mononuclear title complex, [Mn(NCS)(2)(C(11)H(11)N(3)O)(4)], the Mn(II) atom, lying on an inversion center, is coordinated by two monodentate thio-cyanate anions and four monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted octa-hedral geometry. Each complex mol-ecule is linked to four neighboring ones by weak C-H⋯N and C-H⋯S hydrogen bonds, forming a two-dimensional sheet parallel to (001).
在单核标题配合物[Mn(NCS)₂(C₁₁H₁₁N₃O)₄]中，位于对称中心的Mn(II)原子由两个单齿硫氰酸根阴离子和四个单齿1-苯基-3-(1H-1,2,4-三唑-1-基)丙-1-酮配体配位，呈扭曲的八面体几何构型。每个配合物分子通过弱的C-H⋯N和C-H⋯S氢键与四个相邻分子相连，形成平行于(001)的二维片层。
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