具有辅助配体联苯并菲二磺酸钠的双环金属铱(III)配合物的绿色化学发光。
Green chemiluminescence from a bis-cyclometalated iridium(III) complex with an ancillary bathophenanthroline disulfonate ligand.
机构信息
School of Life and Environmental Sciences, Deakin University, Geelong, Victoria 3217, Australia.
出版信息
Analyst. 2011 Aug 7;136(15):3069-72. doi: 10.1039/c1an15315c. Epub 2011 Jun 27.
PMID:21709858
Abstract
The reaction of a fluorinated iridium complex with cerium(IV) and organic reducing agents generates an intense emission with a significant hypsochromic shift compared to contemporary chemically-initiated luminescence from metal complexes.
摘要
氟化铱配合物与铈(IV)和有机还原剂的反应产生强烈的发射，与当代金属配合物的化学引发的发光相比，有显著的蓝移。
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