Delabre U, Richard C, Cazabat A M
Laboratoire de Physique Statistique, Ecole Normale Supérieure, Université Pierre et Marie Curie, CNRS, 24 rue Lhomond, 75231 Paris Cedex 05, France.
J Phys Condens Matter. 2009 Nov 18;21(46):464129. doi: 10.1088/0953-8984/21/46/464129. Epub 2009 Oct 29.
The present paper provides an up to date restatement of the wetting behaviour of the series of cyanobiphenyl liquid crystals (LCs) on usual substrates, i.e. oxidized silicon wafers, water and glycerol, at both the macroscopic and microscopic scale, in the nematic range of temperature. We show that on water the systems are close to a wetting transition, especially 5CB and 7CB. In that case, the wetting behaviour is controlled by the presence of impurities. On a mesoscopic scale, we observe for all our (thin LC film-substrate) systems an identical, complex, but well defined general scenario, not accounted for by the available models. In the last part, we present a study on line tension which results from the specific organization of LCs at the edge of the nematic film. We report preliminary results on two-dimensional film coalescence where this line tension plays a major role.
本文对一系列氰基联苯液晶(LCs)在常见基底(即氧化硅晶片、水和甘油)上,在向列相温度范围内的宏观和微观尺度下的润湿行为进行了最新阐述。我们表明,在水上,这些体系接近润湿转变,特别是5CB和7CB。在这种情况下,润湿行为受杂质的存在控制。在介观尺度上,我们观察到所有(薄液晶薄膜 - 基底)体系都呈现出相同、复杂但明确的一般情况,现有模型无法解释这一情况。在最后一部分,我们对向列相薄膜边缘处液晶的特定排列所产生的线张力进行了研究。我们报告了二维薄膜聚并的初步结果,其中这种线张力起着主要作用。