Iordache Daniela, Niculae Dumitru, Francisc Ioan Hathazi
Energy Research and Modernising Institute--ICEMENERG S.A., 8, Energeticienitor Blvd., 032092 Bucharest 3, Romania.
J Microw Power Electromagn Energy. 2010;44(4):213-21. doi: 10.1080/08327823.2010.11689790.
Soil oil (petroleum) product pollution represents a great environmental threat as it may contaminate the neighboring soils and surface and underground water. Liquid fuel contamination may occur anywhere during oil (petroleum) product transportation, storing, handling and utilization. The polluted soil recovery represents a complex process due to the wide range of physical, chemical and biological properties of soils which should be analyzed in connection with the study of the contaminated soil behavior under the microwave field action. The soil, like any other non-metallic material, can be heated through microwave energy absorption due to the dielectric losses, expressed by its dielectric complex constant. Oil polluted soil behaves differently in a microwave field depending on the nature, structure and amount of the polluting fuel. Decontamination is performed through volatilization and retrieval of organic contaminant volatile components. After decontamination only a soil fixed residue remains, which cannot penetrate the underground anymore. In carrying out the soil recovery process by means of this technology we should also consider the soil characteristics such as: the soil type, temperature, moisture.The first part of the paper presents the theoretical aspects relating to the behavior of the polluted soil samples in the microwave field, as well as their relating experimental data. The experimental data resulting from the analysis of soils with a different level of pollution point out that the degree of pollutant recovery is high, contributing to changing the initial classification of soils from the point of view of pollution. The paper graphically presents the levels of microwave generated and absorbed power in soil samples, soil temperature during experimentations, specific processing parameters in a microwave field. It also presents the constructive solution of the microwave equipment designed for the contaminated soil in situ treatment.
土壤石油(石油制品)污染是一个巨大的环境威胁,因为它可能会污染周边土壤以及地表水和地下水。在石油(石油制品)的运输、储存、处理和使用过程中的任何地方都可能发生液体燃料污染。由于土壤具有广泛的物理、化学和生物学特性,且在微波场作用下对污染土壤行为的研究需要结合这些特性进行分析,因此污染土壤修复是一个复杂的过程。土壤与任何其他非金属材料一样,由于其介电复常数所表示的介电损耗,可以通过吸收微波能量来加热。受油污染的土壤在微波场中的行为因其污染燃料的性质、结构和数量而异。去污是通过有机污染物挥发性成分的挥发和回收来进行的。去污后仅留下土壤固定残留物,它不会再渗入地下。在通过这项技术进行土壤修复过程中,我们还应考虑土壤特性,如:土壤类型、温度、湿度。本文的第一部分介绍了与污染土壤样品在微波场中的行为相关的理论方面,以及相关的实验数据。对不同污染程度土壤的分析得出的实验数据表明,污染物的回收率很高,从污染角度来看有助于改变土壤的初始分类。本文以图表形式展示了土壤样品中产生和吸收的微波功率水平、实验过程中的土壤温度、微波场中的特定处理参数。还展示了为原位处理受污染土壤而设计的微波设备的结构解决方案。