双{2-[(E)-(4-氟苄基)亚氨基甲基]-6-甲氧基苯酚根合}钯(II)
Bis{2-[(E)-(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolato}palladium(II).
作者信息
Bahron Hadariah, Mohd Tajuddin Amalina, Ibrahim Wan Nazihah Wan, Hemamalini Madhukar, Fun Hoong-Kun
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m759-60. doi: 10.1107/S1600536811017739. Epub 2011 May 20.
In the title compound, [Pd(C(15)H(13)FNO(2))(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from the two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phen-oxy ligands, forming a square-planar geometry. The two N atoms and the two O atoms around the Pd(II) atom are trans to each other. The dihedral angle between the two fluoro-substituted benzene rings is 39.03 (6)°. The mol-ecular structure is stabilized by an intra-molecular C-H⋯O hydrogen bond. In the crystal, weak inter-molecular C-H⋯π inter-actions occur.
在标题化合物[Pd(C₁₅H₁₃FNO₂)₂]中，Pd(II)原子由两个2-[(4-氟苄基)亚氨基甲基]-6-甲氧基苯氧基配体的两个N原子和两个O原子四配位，形成平面正方形几何构型。Pd(II)原子周围的两个N原子和两个O原子彼此反式排列。两个氟取代苯环之间的二面角为39.03(6)°。分子结构通过分子内C—H⋯O氢键得以稳定。在晶体中，存在弱的分子间C—H⋯π相互作用。
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