Shi Haochen, Gao Feng, Qi Jingang
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1255-6. doi: 10.1107/S1600536811032624. Epub 2011 Aug 17.
The title compound, Cu(C(9)H(6)N(3)O(2))(OH)(H(2)O)(2), adopts a chain motif along [010] in which the Cu(II) atoms are bridged by hy-droxy groups and 4-(1,2,4-triazol-4-yl)benzoate (tab) ligands. The Cu(II) atom lies on an inversion center and is six-coordinated by two N atoms from two tab ligands, two hy-droxy groups and two water mol-ecules, giving a distorted octa-hedral geometry. The hy-droxy group and the tab ligand are located on a mirror plane. One of the water H atoms is disordered over two positions with equal occupancy factors. Inter-molecular O-H⋯O hydrogen bonds extend the chains into a layer parallel to (100) and C-H⋯O hydrogen bonds connect the layers into a three-dimensional network.