Jin Xu-Dong, Wang Hai-Bo, Jin Yue-Hong
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):o2233. doi: 10.1107/S1600536811030522. Epub 2011 Aug 2.
A novel Schiff base compound, C(20)H(27)NO(2), was obtained by a condensation of rimantadine and 2-hy-droxy-4-meth-oxy-benzaldehyde. An intra-molecular O-H⋯N hydrogen bond supports the phenol-imine tautomeric form. The adamantane and imino-methyl-4-meth-oxy-phenol units are arranged in a folded conformation [C-N-C-C torsion angle = 110.9 (3)°]. In the crystal, highly hydro-phobic adamantane moieties are inserted between the imino-methyl-4-meth-oxy-phenol units in a sandwich-like arrangement along the c axis.