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rac-2-{[1-(1-Adamant-yl)eth-yl]imino-meth-yl}-5-meth-oxy-phenol.

作者信息

Jin Xu-Dong, Wang Hai-Bo, Jin Yue-Hong

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):o2233. doi: 10.1107/S1600536811030522. Epub 2011 Aug 2.

Abstract

A novel Schiff base compound, C(20)H(27)NO(2), was obtained by a condensation of rimantadine and 2-hy-droxy-4-meth-oxy-benzaldehyde. An intra-molecular O-H⋯N hydrogen bond supports the phenol-imine tautomeric form. The adamantane and imino-methyl-4-meth-oxy-phenol units are arranged in a folded conformation [C-N-C-C torsion angle = 110.9 (3)°]. In the crystal, highly hydro-phobic adamantane moieties are inserted between the imino-methyl-4-meth-oxy-phenol units in a sandwich-like arrangement along the c axis.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64b/3200738/ab0e6bb80a18/e-67-o2233-fig1.jpg

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