Rivera Augusto, Quiroga Diego, Ríos-Motta Jaime, Fejfarová Karla, Dušek Michal
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):o2297. doi: 10.1107/S1600536811031205. Epub 2011 Aug 11.
The complete molecule of the title compound, C(31)H(42)N(2)O(6), is generated by crystallographic twofold symmetry, with one C atom lying on the axis. The dihedral angle between the aromatic rings is 57.03 (6)°. The central heterocyclic ring adopts a half-chair conformation. The mol-ecular conformation is stabilized by two intra-molecular O-H⋯N hydrogen bonds with the N atoms of the heterocyclic ring as the acceptors. In the crystal, mol-ecules are linked into chains along the c axis by non-classical C-H⋯O hydrogen bonds.
标题化合物C(31)H(42)N(2)O(6)的完整分子由晶体学二重对称性产生,有一个C原子位于对称轴上。芳环之间的二面角为57.03 (6)°。中心杂环呈半椅构象。分子构象通过两个分子内O-H⋯N氢键得以稳定,其中杂环的N原子作为受体。在晶体中,分子通过非经典的C-H⋯O氢键沿c轴连接成链。