（乙腈-κN）[2-（二苯基膦基）乙胺-κN，P][（1,2,3,4,5-η）-1,2,3,4,5-五甲基环戊二烯基]铁（II）六氟磷酸四氢呋喃单溶剂合物
(Acetonitrile-κN)[2-(diphenylphosphan-yl)ethanamine-κN,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate.
作者信息
Lee Kajin, Rominger Frank, Limbach Michael
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1135. doi: 10.1107/S1600536811028832. Epub 2011 Jul 23.
Abstract
In the title cationic Cp()Fe(II) complex, [Fe(C(10)H(15))(CH(3)CN)(C(14)H(16)NP)]PF(6)·C(4)H(8)O, the metal ion is coordinated by the η(5)-Cp ring as well as the P and N atoms of the chelating 2-(diphenyl-phosphino)ethyl-amine ligand and an additional acetonitrile mol-ecule in a piano-chair conformation. The PF(6) (-) anion is disordered over two sets of sites with occupancies of 0.779 (7) and 0.221 (7).
摘要
在标题阳离子 Cp()Fe(II) 配合物 [Fe(C₁₀H₁₅)(CH₃CN)(C₁₄H₁₆NP)]PF₆·C₄H₈O 中，金属离子由 η⁵-Cp 环以及螯合的 2-(二苯基膦基)乙胺配体的 P 和 N 原子以及处于椅式构象的另一个乙腈分子配位。PF₆⁻ 阴离子在两组位置上无序分布，占有率分别为 0.779 (7) 和 0.221 (7)。
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