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2-(2-氯-6,7-二甲基喹啉-3-基)-2,3-二氢喹啉-4(1H)-酮

2-(2-Chloro-6,7-dimethyl-quinolin-3-yl)-2,3-dihydro-quinolin-4(1H)-one.

作者信息

Benzerka Saida, Bouraiou Abdelmalek, Bouacida Sofiane, Roisnel Thierry, Belfaitah Ali

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2084-5. doi: 10.1107/S1600536811028170. Epub 2011 Jul 23.

Abstract

In the title mol-ecule, C(20)H(17)ClN(2)O, the dihedral angle between the mean plane of the quinoline ring system and the benzene ring of the dihydro-quinolinone moiety is 57.84 (8)°. In the crystal, mol-ecules are linked into centrosymmetric dimers via pairs of inter-molecular N-H⋯N hydrogen bonds. These dimers are further stabilized by weak π-π stacking inter-actions between pyridine rings with a centroid-centroid distance of 3.9414 (12) Å.

摘要

在标题分子C(20)H(17)ClN(2)O中,喹啉环系的平均平面与二氢喹啉酮部分的苯环之间的二面角为57.84 (8)°。在晶体中,分子通过分子间N-H⋯N氢键对连接成中心对称二聚体。这些二聚体通过吡啶环之间的弱π-π堆积相互作用进一步稳定,质心间距为3.9414 (12) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec05/3213526/0b62feeb8d34/e-67-o2084-fig1.jpg

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