聚[四-双-(μ-苯-1,2-二羧基-ato)-二-μ-甲酸根-五锶(II)]
Poly[tetra-kis-(μ-benzene-1,2-dicarboxyl-ato)di-μ-formato-penta-strontium(II)].
作者信息
Cheng Pei-Chi, Zhan Jun-Xiang, Wu Cheng-You, Lin Chia-Her
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1647. doi: 10.1107/S1600536811044977. Epub 2011 Nov 2.
Abstract
The asymmetric unit of the title complex, Sr(5)(C(8)H(4)O(4))(4)(HCO(2))(2), contains three independent Sr(II) ions, one of which is located on an inversion center. In the crystal, the Sr(II) ions (coordination numbers 8, 9 and 12) are connected by two crystallographically distinct benzene-1,2-dicarboxyl-ate ligands and one formate ligand, forming a two-dimensional polymer parallel to (001).
摘要
标题配合物[Sr₅(C₈H₄O₄)₄(HCO₂)₂]ₙ的不对称单元包含三个独立的Sr(II)离子，其中一个位于对称中心上。在晶体中，Sr(II)离子（配位数分别为8、9和12）通过两种晶体学上不同的苯-1,2-二甲酸酯配体和一个甲酸酯配体相连，形成一个平行于(001)的二维聚合物。
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