四水合双-{5-[4-(咪唑-1-基-κN)苯基]四唑基}锰(II)
Tetra-aqua-bis-{5-[4-(imidazol-1-yl-κN)phen-yl]tetra-zolido}manganese(II).
作者信息
Cheng Xiao-Chun
机构信息
Faculty of Life Science and Chemical Engineering, Huaiyin Institute of Technology, Huaian 223003, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1757. doi: 10.1107/S1600536811047428. Epub 2011 Nov 12.
In the title complex, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)], the Mn(2+) cation is located on a twofold rotation axis and is coordinated by two N atoms from two 5-[4-(imidazol-1-yl)phen-yl]tetra-zolide ligands and four O atoms from four water mol-ecules, displaying a distorted MnN(2)O(4) octa-hedral geometry. The crystal structure is stabilized by intermolecular O-H⋯N hydrogen bonds involving the coordinated water mol-ecules and the N atoms of the tetra-zolide group.
在标题配合物[Mn(C₁₀H₇N₆)₂(H₂O)₄]中，Mn²⁺阳离子位于二重旋转轴上，由来自两个5-[4-(咪唑-1-基)苯基]四唑配体的两个N原子和来自四个水分子的四个O原子配位，呈现出扭曲的MnN₂O₄八面体几何构型。晶体结构通过涉及配位水分子和四唑基团N原子的分子间O—H⋯N氢键得以稳定。
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