Horkaew Jirapa, Chantrapromma Suchada, Fun Hoong-Kun
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):o2985. doi: 10.1107/S1600536811041535. Epub 2011 Oct 22.
The title benzohydrazide derivative, C(17)H(18)N(2)O(5), exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 19.41 (5)°. The two meth-oxy groups at the meta positions of the trimeth-oxy-benzene group are almost coplanar with the ring [C-O-C-C = 1.62 (16) and 178.33 (10)°], whereas the third meth-oxy group, at the para position, is (+)-synclinal with the ring. In the crystal, mol-ecules are linked by N-H⋯O and bifurcated O-H⋯(N,O) hydrogen bonds, as well as weak C-H⋯O inter-actions, into sheets lying parallel to the ac plane. A C-H⋯π inter-action also occurs.
标题苯甲酰肼衍生物C(17)H(18)N(2)O(5),相对于C=N双键以反式构象存在。苯环之间的二面角为19.41 (5)°。三甲氧基苯基团间位的两个甲氧基与环几乎共面[C-O-C-C = 1.62 (16) 和178.33 (10)°],而对位的第三个甲氧基与环呈(+)-顺错构象。在晶体中,分子通过N-H⋯O和分叉的O-H⋯(N,O)氢键以及弱的C-H⋯O相互作用连接成平行于ac平面的片层。还存在C-H⋯π相互作用。