Molecular Electronics and Photonics, INPAC, Katholieke Universiteit Leuven, Leuven, Belgium.
Phys Chem Chem Phys. 2012 Feb 14;14(6):1860-4. doi: 10.1039/c2cp23311h. Epub 2012 Jan 10.
Faraday rotation and its dispersion have been measured and calculated in the 400-800 nm wavelength range for a set of saturated organic liquids. The resulting Verdet constants are fitted and trends are analyzed. Comparisons are made to both the polarizability and diamagnetic susceptibility. The data are applied to a connectivity index model, allowing prediction of Verdet constants of aliphatic organic liquids from 400 to 800 nm. The observed correlations and connectivity model improve the understanding of Faraday rotation in diamagnetic materials, allowing for future optimization.
已在 400-800nm 波长范围内测量和计算了一组饱和有机液体的法拉第旋转及其色散。拟合了得到的Verdet 常数,并分析了趋势。将其与极化率和抗磁性磁化率进行了比较。这些数据应用于连接性指数模型,可预测从 400nm 到 800nm 的脂肪族有机液体的Verdet 常数。观察到的相关性和连接性模型提高了对抗磁性材料中法拉第旋转的理解,为未来的优化提供了依据。