Department of Technology, University Parthenope of Naples, Italy.
Waste Manag. 2012 Jun;32(6):1179-85. doi: 10.1016/j.wasman.2011.12.013. Epub 2012 Jan 13.
Fly ash from municipal solid waste incinerators (MSWI) is classified as hazardous in the European Waste Catalogue. Proper stabilization processes should be required before any management option is put into practice. Due to the inorganic nature of MSWI fly ash, cementitious stabilization processes are worthy of consideration. However, the effectiveness of such processes can be severely compromised by the high content of soluble chlorides and sulphates. In this paper, a preliminary washing treatment has been optimized to remove as much as possible soluble salts by employing as little as possible water. Two different operating conditions (single-step and two-step) have been developed to this scope. Furthermore, it has been demonstrated that stabilized systems containing 20% of binder are suitable for safer disposal as well as for material recovery in the field of road basement (cement bound granular material layer). Three commercially available cements (pozzolanic, limestone and slag) have been employed as binders.
城市生活垃圾焚烧飞灰(MSWI)在欧洲废物目录中被归类为危险废物。在实施任何管理方案之前,应要求采用适当的稳定化工艺。由于 MSWI 飞灰的无机性质,胶凝稳定化工艺值得考虑。然而,高含量的可溶性氯化物和硫酸盐会严重影响这些工艺的效果。在本文中,通过采用尽可能少的水,优化了一种初步的洗涤处理,以尽可能多地去除可溶性盐。为此目的,开发了两种不同的操作条件(单步和两步)。此外,已经证明,含有 20%粘结剂的稳定化系统适合于更安全的处置,以及在道路基层(水泥结合粒状材料层)领域进行材料回收。使用了三种市售水泥(火山灰、石灰石和矿渣)作为粘结剂。