迭代 Shimizu 非羟醛缩合方法用于立体选择性合成 callystatin A 的 C13-C22 片段。
An iterative Shimizu non-aldol approach for the stereoselective synthesis of C13-C22 fragment of callystatin A.
机构信息
Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India.
出版信息
Org Biomol Chem. 2012 Mar 7;10(9):1750-3. doi: 10.1039/c2ob06838a. Epub 2012 Jan 27.
PMID:22286400
Abstract
An efficient synthesis of the polypropionate framework of callystatin A has been achieved by utilizing the Shimizu reaction in an iterative fashion.
摘要
通过以迭代方式利用 Shimizu 反应，实现了 calystatin A 的聚丙酸盐骨架的有效合成。
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