NAST Center and Department of Chemical Science and Technology, University of Rome Tor Vergata, Via della Ricerca Scientifica 1, I-00133 Rome, Italy.
J Phys Condens Matter. 2012 Apr 11;24(14):142202. doi: 10.1088/0953-8984/24/14/142202. Epub 2012 Mar 5.
We report the local electronic and magnetic properties of Bi(2)FeCrO(6) nanostructures by element-specific polarized x-ray techniques. Sizable magnetic ordering in the remanent state is observed at room temperature for both Fe and Cr ions. The Bi(2)FeCrO(6) system offers an example of d(5)-d(3) magnetic superexchange interaction with a magnetic order for both Fe and Cr, which are both formally in the + 3 valence state. The results suggest a coexistence of antiferromagnetic and ferromagnetic superexchange interaction between Fe and Cr spins in the nanostructures at the remanent state and at room temperature.
我们通过元素特异性极化 X 射线技术报告了 Bi(2)FeCrO(6) 纳米结构的局部电子和磁性质。在室温下,Fe 和 Cr 离子在剩磁状态下均观察到可观的磁有序。Bi(2)FeCrO(6) 体系提供了一个 d(5)-d(3) 磁超交换相互作用的例子,其中 Fe 和 Cr 均具有磁有序,它们的价态均为 +3。结果表明,在纳米结构的剩磁状态和室温下,Fe 和 Cr 自旋之间存在反铁磁和铁磁超交换相互作用的共存。