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玻璃形成液体中的静态点到集相关性。

Static point-to-set correlations in glass-forming liquids.

作者信息

Berthier Ludovic, Kob Walter

机构信息

Laboratoire Charles Coulomb, UMR 5221, CNRS and Université Montpellier 2, 34095 Montpellier, France.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2012 Jan;85(1 Pt 1):011102. doi: 10.1103/PhysRevE.85.011102. Epub 2012 Jan 3.

Abstract

We analyze static point-to-set correlations in glass-forming liquids. The generic idea is to freeze the position of a set of particles in an equilibrium configuration and to perform sampling in the presence of this additional constraint. Qualitatively different geometries for the confining set of particles are considered and a detailed comparison of resulting static and dynamic correlation functions is performed. Our results reveal the existence of static spatial correlations not detected by conventional two-body correlators, which appear to be decoupled from, and shorter-ranged than, dynamical length scales characterizing dynamic heterogeneity. We find that the dynamics slows down dramatically under confinement, which suggests new ways to investigate the glass transition. Our results indicate that the geometry in which particles are randomly pinned is the best candidate to study static correlations.

摘要

我们分析了玻璃形成液体中的静态点到集相关性。一般的想法是将一组粒子的位置冻结在平衡构型中,并在这种额外约束的情况下进行采样。我们考虑了限制粒子集的定性不同的几何形状,并对所得的静态和动态相关函数进行了详细比较。我们的结果揭示了传统两体相关器未检测到的静态空间相关性的存在,这些相关性似乎与表征动态不均匀性的动态长度尺度解耦且范围更短。我们发现,在受限情况下动力学显著减慢,这为研究玻璃转变提供了新方法。我们的结果表明,粒子被随机固定的几何形状是研究静态相关性的最佳候选者。

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