消旋-2-(2-氯-6-甲基喹啉-3-基)-2,3-二氢喹啉-4(1H)-酮
rac-2-(2-Chloro-6-methyl-quinolin-3-yl)-2,3-dihydro-quinolin-4(1H)-one.
作者信息
Bouraiou Abdelmalek, Bouacida Sofiane, Bertrand Carboni, Roisnel Thierry, Belfaitah Ali
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):o1701-2. doi: 10.1107/S1600536812020831. Epub 2012 May 12.
Abstract
In the title compound, C(19)H(15)ClN(2)O, the quinoline ring forms a dihedral angle of 43.24 (1)° with the benzene ring of the dihydroquinolinyl system. In the crystal, mol-ecules are linked through a single weak C-H⋯O hydrogen bond, forming ribbons which extend along (100), giving alternating zigzag mol-ecular layers which stack down the b-axis direction.
摘要
在标题化合物C₁₉H₁₅ClN₂O中，喹啉环与二氢喹啉基体系的苯环形成43.24（1）°的二面角。在晶体中，分子通过单一的弱C—H⋯O氢键相连，形成沿（100）方向延伸的带状结构，产生交替的锯齿状分子层，这些分子层沿b轴方向堆叠。
相似文献
1
rac-2-(2-Chloro-6-methyl-quinolin-3-yl)-2,3-dihydro-quinolin-4(1H)-one.
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):o1701-2. doi: 10.1107/S1600536812020831. Epub 2012 May 12.
2
2-(2-Chloro-6,7-dimethyl-quinolin-3-yl)-2,3-dihydro-quinolin-4(1H)-one.
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2084-5. doi: 10.1107/S1600536811028170. Epub 2011 Jul 23.
3
3-Hy-droxy-1-methyl-2-[4-(piperidin-1-yl)phen-yl]quinolin-4(1H)-one.
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 19;67(Pt 3):o654. doi: 10.1107/S1600536811005046.
4
1-[5-(2-Chloro-phen-yl)-5-hy-droxy-3-methyl-4,5-dihydro-1H-pyrazol-1-yl]-ethanone.
Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):o839. doi: 10.1107/S1600536812007283. Epub 2012 Feb 24.
5
1-[(2-Chloro-7,8-dimethyl-quinolin-3-yl)meth-yl]pyridin-2(1H)-one.
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 31;66(Pt 4):o1001. doi: 10.1107/S1600536810011505.
6
1-[5-(4-Chloro-phen-yl)-3-(4-hy-droxy-phen-yl)-4,5-dihydro-1H-pyrazol-1-yl]-ethanone.
Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):o818. doi: 10.1107/S1600536812006885. Epub 2012 Feb 24.
7
6-Chloro-2-methyl-4-phenyl-3-[1-phenyl-5-(2-thien-yl)-4,5-dihydro-1H-pyrazol-3-yl]quinoline.
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 10;65(Pt 11):o2707-8. doi: 10.1107/S1600536809040239.
8
(Z)-1-(2-Chloro-phen-yl)-3-methyl-4-[2-(4-nitro-phen-yl)hydrazin-1-yl-idene]-1H-pyrazol-5(4H)-one.
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2351-2. doi: 10.1107/S1600536812029790. Epub 2012 Jul 7.
9
4-Chloro-benzaldehyde (1-isobutyl-1H-imidazo[4,5-c]quinolin-4-yl)hydrazone monohydrate.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 15;67(Pt 2):o407-8. doi: 10.1107/S1600536811001577.
10
4-(4-Chloro-phen-yl)-2,6-bis-(1H-indol-3-yl)-1,4-dihydro-pyridine-3,5-dicarbo-nitrile ethanol monosolvate.
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1300-1. doi: 10.1107/S1600536812013906. Epub 2012 Apr 4.
引用本文的文献
1
Crystal structure of ethyl 2-chloro-5,8-di-meth-oxy-quinoline-3-carboxyl-ate.
Acta Crystallogr Sect E Struct Rep Online. 2014 Aug 1;70(Pt 9):o964-5. doi: 10.1107/S1600536814017309. eCollection 2014 Sep 1.
本文引用的文献
1
2-(2-Chloro-6,7-dimethyl-quinolin-3-yl)-2,3-dihydro-quinolin-4(1H)-one.
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2084-5. doi: 10.1107/S1600536811028170. Epub 2011 Jul 23.
2
A short history of SHELX.
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
Zotero 插件